A lot depends on what you're looking for out of a set of headers. Long tube tuned headers give better higher rpm power, but at the expense of ground clearance and possible installation issues...steering box and inner fenders. Tri-Y headers are known for torque production. Block hugger headers kind of split the difference and have the fewest installation issues and can usually connect to factory type pipes. You need to decide what you're looking for performance-wise then find the headers that best fit those needs.
That GM 350HO is a fine engine...I have it in one of my cars (not a Vette). I have Sanderson block hugger headers on it and am very satisfied.
Regardless of the headers you end up with, spend the extra and get them coated...ceramic, Jet Hot or similar. It will pay off in longer life, better looks and far less grief.