I have a 71 454 without air or pollution pump with power steering,
and am wondering about belt routing and pulleys. I currently have
a 2 groove crank pulley, a 3 groove fan pulley,a 2 groove PS, and a single groove
alt pulley. The alignment of the grooves only allows one belt to be
used, which of course is not correct.
Any help or info would be appreciated.

Belt routings are in the AIM. Maybe someone with a '71 AIM will help, but if you're going to own the car any length of time, the AIM is a worthwhile investment.